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Fulleranes are a special class of carbon molecules derived from fullerenes whose double bonds are partially or at least theoretically fully saturated by hydrogen. The hydrogenation changes the chemical properties of fullerenes which can become susceptible to substitution reactions as opposed to addition reactions to the double bonds (present in common fullerenes). One of the most intriguing aspects of fulleranes is the fact that they have been thought to exist in the interstellar medium or even in certain circumstellar media. qFulleranes: The Hydrogenated Fullerenesq presents the state of the art research, synthesis and properties of these molecules.This book also includes astrophysicists' and astrochemists' expectations regarding the presence of these molecules in space.Molecules with abutting pentagons are well known to be unstable structural configurations in organic chemistry a€“ which ... 1986) a€“ but then theoreticians often seem able to get the answers they are looking for. ... Schmalz, Doug Klein and co-workers in Galveston (1988). ... David Walton and I, somewhat later, published a paper which used related fairly simple, semi-quantitative, arguments to predict smallanbsp;...

Author: Franco Cataldo, Susana Iglesias-Groth
Publisher:Springer Science & Business Media - 2010-08-09

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